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The key thing in a good system of units is to define units in a way that depends only on physical properties of nature.
Ideally (or basically necessarily?) the starting point generally has to be discrete phenomena, e.g.
What we don't want is to have macroscopics measurement artifacts, (or even worse, the size of body parts! Inset dick joke) as you can always make a bar slightly more or less wide. And even metals evaporate over time! Though the mad people of the Avogadro project still attempted otherwise well into the 2010s!
Standards of measure that don't depend on artifacts are known as intrinsic standards.

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